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Bioremediation for Sustainable Environmental Cleanup

lethal than any other form (Ullrich et al. 2001). Selenium removal from contaminated environments

by biomethylation has also been reported (Adriano et al. 2004).

9.3.3 Oxidation/Reduction Mechanism

Microbes use oxidation/reduction reactions to decrease Cr, Se, Hg and As. Dissimilatory and

assimilatory reactions are the two main classes into which the oxidation/reduction reactions are

separated. In dissimilatory reactions, the metal(loid)s do not play any specific function in the

growth of microbes (Bolan et al. 2014). They are found by accidental reductions linked to microbial

oxidations to produce H2, alcohols, simple organic acids and aromatic compounds (Holden and

Adams 2003). In assimilatory reactions, the growth of microbes is promoted by metal(loid) to assist

as the terminal e- acceptor (Holden and Adams, 2003).

Bacteria reduce the toxicity of Cr(VI) and Hg(II) to less toxic forms by enzymatic reduction

(Choppala et al. 2015). Astudy has shown that Se(VI) reduces to Se(0) from wastewater by anaerobic

bacteria (Nejad et al. 2018). This remediation strategy has been proven as a successful approach

for wastewater treatment. The oxidation mechanism’s capability to transmute As(III) to As(V) has

been found in archaebacterium Sulfolobus acidocaldarius (Lindström and Sehlin 1989). It has been

reported that in an aqueous medium, in the presence of Fe(III), the oxidation rate of As(III) to As(V)

is enhanced. As(V) are less toxic than As(III) and firmly bound with the inorganic soil components

that result in immobilization and bioremediation through microbial oxidation (Lindström and

Sehlin 1989). A similar reduction mechanism is followed by Cr(VI) to Cr(III) in the soil component.

A study reported that Bacillus sp. isolated from the Cr-contaminated landfill reduces the potent

Cr(VI) to a lesser toxic form Cr(III) (Bolan et al. 2003). In situations with a convenient source of

e- (Fe(II)), chromate (Cr(VI)) can be reduced to Cr(III), and microbial Cr(VI) reduction takes place

in the presence of organic matter as an e- donor (Bolan et al. 2014).

9.3.4 Precipitation

In polluted soils with basic concentrations and several anions present including phosphate, carbonate,

sulfate and hydroxide, the precipitation mechanism of metal(loid)s removal has been discovered

(Ok et al. 2010). Metal(loid) precipitation like Pb and Cu with carbonate and phosphate is an

immobilization mechanism of bioremediation for elimination from soil or wastewater (McGowen

et al. 2001). Studies show that phosphate reduced the discharge of Zn, Pb and Cd (McGowen et al.

2001). Similarly, additional research presented the precipitation of Cr(III) by the addition of lime

by enhancing the soil pH (Bolan et al. 2003). The existence of iron oxyhydroxides causes changes

in the surface chemicals present on the substrate and often leads to co-precipitation of metal(loid)s

(Bolan et al. 2014, McGowen et al. 2001). The Pb(II) precipitates at pH 4 by the effect of ferric

oxyhydroxides with hydroxide chloride [Pb(OH)Cl], chloride (PbCl2) and carbonate (PbCO3),

while reacting with Mg/Al in an aqueous solution with hydroxides (Violante et al. 2007). Usually,

phosphate compounds are added to the soil to prevent heavy metal(loid) leaching (Bolan et al.

2014). Stability of metallic phosphates is found in the following order Pb > Cu > Zn (Bolan et al.

2003).

9.3.5 Biological Transformation

Metal(loids)s solubility can be enhanced by microbial processes (Krebs et al. 1997). Microbes raise

the bioavailability that results in immobilization (Park et al. 2011). Solubilization of the metalloids

by microbes is grouped into two categories: Autotrophic (chemolithotrophic) and heterotrophic

(chemoorganotrophic) (Krebs et al. 1997). Immobilization via microbes of metals could possibly

be brought into the framework by the means of reduction, precipitation, biosorption, accumulation,

sequestration and localization (Gadd 2010). Metal is removed through adsorption when metal(loid)s